Thirty one people have been arrested in Ferguson, Missouri, during another night of angry protests.
Ferguson unrest flared hours after President Barack Obama called for calm following the fatal police shooting of unarmed black teenager Michael Brown on August 9.
Attorney General Eric Holder is due to visit Ferguson on Wednesday, August 20, to meet federal officials investigating the killing.
The National Guard has been deployed to support police operations.
Missouri Governor Jay Nixon announced the National Guard deployment on August 18, in addition to lifting a night-time curfew imposed on the weekend.
The killing of Michael Brown by a white policeman, named Darren Wilson, in a street has inflamed racial tensions in the largely black community of Ferguson.
Officer Darren Wilson shot Michael Brown on August 9 after reportedly stopping him for walking in the street.
Police Captain Ron Johnson said officers were forced to use tear gas and stun grenades on Tuesday after they came under “heavy gunfire” and were attacked with petrol bombs and bottles.
He said two people were hit by gunfire from demonstrators, insisting that officers did not use their weapons.
Ron Johnson appealed to demonstrators to protest in the daytime to prevent a “tiny minority of law breakers” from deliberately sparking violence.
“Anyone who has been at these protests understands that there is a dangerous dynamic in the night: it allows a small number of violent agitators to hide in the crowd and then attempt to create chaos,” he told journalists.
Those arrested include people from other states, including New York and California, Capt. Ron Johnson said. Correspondents say this suggests the protests are becoming more organized.
In an earlier statement, Attorney General Eric Holder said he would “personally travel” to Ferguson on Wednesday to meet FBI investigators and prosecutors.
“I realize there is tremendous interest in the facts of the incident that led to Michael Brown’s death, but I ask for the public patience as we conduct this investigation,” he said.
Eric Holder added that the investigation into the shooting of 18-year-old Michael Brown was “a critical step in restoring trust between law enforcement and the community, not just in Ferguson, but beyond”.
Separately, President Barack Obama said he understood the “passions and anger” provoked by the death of the teenager.
Barack Obama also stressed that giving into anger “by looting or carrying guns and even attacking the police only serves to raise tensions and stir chaos”.
The president said he recognized that in many communities in the US a “gulf of mistrust” existed between local residents and law enforcement.
“In too many communities, too many young men of color are left behind and seen only as objects of fear,” he said.
Earlier, Dr. Michael Baden, a former New York pathologist hired by Michael Brown’s family, performed an independent post-mortem examination.
Dr. Michael Baden said he believed six bullets struck the teenager, two of which may have re-entered.
“All of the gunshot wounds could have been survivable, except the one at the top of the head,” he said.
Dr. Michael Baden said there were no signs of a struggle, as abrasions around Michael Brown’s face were likely from falling to the pavement after being shot.
He also believed Darren Wilson did not shoot him at close range as there was no gunpowder residue on his body, suggesting the officer was more than 2ft away.
Witnesses have said Michael Brown was shot as he held his hands up in a position of surrender, while the police and supporters of Darren Wilson have said he fired during a fight with the teenager.
Officer Darren Wilson has been suspended with pay since the shooting.
Michael Brown’s family has called for his arrest.
Another post-mortem on Michael Brown will be conducted by the US justice department, in addition to examinations by Dr. Michael Baden and St Louis county officials.
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